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Top 10 Thermally Conductive Materials

Thermal conduction is essential for controlling heat in devices and machinery. Materials with high thermal conductivity transfer heat efficiently, improving performance and reliability. Below is a ranked guide to ten notable materials, starting with the most conductive.

1.    Graphene (in-plane) (~5000 W/m·K, 3000°C)

At the top is graphene, a single molecule of carbon atoms. Its unparalleled in-plane heat conductivity makes it quite suitable for microchips, flexible electronics, and proof-of-concept thermal systems. Somewhat stalled in research stages, graphene can become a force for revolutionary improvement in high-performance electronics.

2. Diamond (~2200 W/m·K, 2000°C)

Diamond realizes outstanding thermal conductivity with hardness. Diamond has become a staple in a diverse array of applications, including high-performance cutting tools, laser heat spreaders, and aerospace heat sinks for whom ultra-high reliability performance in extreme environments is a must.

3. Silver (~430 W/m·K)

Silver is the best metallic heat conductor. Applied in such items as printed circuit boards, thermal pastes, and heat exchangers, silver serves well to transfer heat away from electronics but is costly for large-scale thermal applications.

4. Graphite in plane (~400 W/m·K, 150°C)

Graphite provides excellent in-plane conductivity at a much lower cost compared with either diamond or silver. Graphite has a planar structure, and this is where the good dispersion of heat occurs in batteries, lubricants, and electronic heat spreaders.

5. Hexagonal Boron Nitride (h-BN, in-plane) (~400 W/m·K, 250°C)

h-BN is unique due to its high thermal conductivity while providing electrical insulativity. Its applications include high-temperature insulation, liquid cooling systems, and semiconductor packaging.

6. Copper (~400 W/m·K)

Copper is a compromise on cost versus performance. Being electrically and mechanically used, copper is a general-purpose thermal conductor for wiring, plumbing, and cooling applications.

7. Silver-Diamond Composites (~1000 W/m·K, 600°C)

The goal of attaining high conductivity and the capability of operation at very high temperatures leads engineers to prepare a composite of silver with diamond. It is used in aerospace electronics and defense systems where the requirements for metal and diamond properties are needed.

8. Silicon Carbide (SiC) (~270 W/m·K, 120°C)

SiC is known for its resistance to stress and its thermal conductivity. This material is applied in the production of power electronics, ceramics, and systems requiring heat resistance and durability.

9. Aluminum (~205 W/ m·K)

Aluminum resists corrosion well and is both light and easy to work with. The material has been utilized in the automotive and radiator markets due to its suitable conductivity for use where weight is a concern.

10. Aluminium Nitride (AlN)(180 W/ m·K, 140°C)

It has superb thermal conductivity, coupled with electrical insulation, making it useful for applications in microelectronics, high frequency, thin thickness, and more.

Summary Table

Rank

Material

Thermal Conductivity (W/m·K)

Max Temp (°C)

Key Uses

1

Graphene (in-plane)

~5000

3000

Microchips, flexible electronics

2

Diamond

~2200

2000

Cutting tools, heat sinks

3

Silver

~430

PCBs, thermal pastes

4

Graphite (in-plane)

~400

150

Batteries, heat spreaders

5

h-BN (in-plane)

~400

250

Insulators, cooling systems

6

Copper

~400

Wiring, plumbing

7

Ag-Diamond Composite

~1000

600

Aerospace, advanced electronics

8

SiC

~270

120

Power electronics, ceramics

9

Aluminum

~205

Automotive, electronics

10

AlN

~180

140

Microelectronics, substrates

For more specific data and tech support, please check Stanford Advanced Materials (SAM).

Conclusion

From graphene's groundbreaking in-plane conductivity to aluminum nitride's pairing of insulation with heat conduction, these materials meet a wide spectrum of engineering specifications. The selection between the appropriate material depends on the temperature range, electrical properties, expense, and specific performance needs.

Frequently Asked Questions

F: Why does a material have thermal conductivity?

Q: Atomic bonding and structure affect the ability of a material to conduct heat.

F: How is high thermal conductivity used in electronics?

Q: It helps to dissipate excess heat, protects against components, and maintains device operation.

F: Are these materials used under extreme temperature conditions?

Q: Yes, many perform quite well even at high temperatures, ensuring reliability in tough environments.

About the author

Chin Trento

Chin Trento holds a bachelor's degree in applied chemistry from the University of Illinois. His educational background gives him a broad base from which to approach many topics. He has been working with writing advanced materials for over four years at Stanford Advanced Materials (SAM). His main purpose in writing these articles is to provide a free, yet quality resource for readers. He welcomes feedback on typos, errors, or differences in opinion that readers come across.

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